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氯化钙体系制备的褐藻酸钙凝胶特性的研究
许加超1, 卢伟丽1, 高昕1, 付晓婷1, 薛长湖1
中国海洋大学食品科学与工程学院,青岛 266003
摘要:
采用氯化钙体系制作的褐藻酸钠凝胶,其性能受氯化钙浓度、温度及褐藻酸钠的甘露糖醛酸(M)及古罗糖醛酸(G)的比值(即M/G)影响较大。当氯化钙溶液的温度为50℃、浓度为20%时,凝胶的性能最佳;高G的褐藻酸钙凝胶的拉伸强度优于高M的,但是吸水性能却不如高M的褐藻酸钙凝胶。通过红外光谱分析褐藻酸钠成凝胶前后结构变化,主要是-OH峰位置向高波数方向偏移以及C-H伸缩振动变弱,这是褐藻酸钠与Ca2+之间发生交链的结果。
关键词:  M/G  褐藻酸钠凝胶  氯化钙
DOI:
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基金项目:山东省科技攻关项目(2007GG10005008158)资助
Study on the properties of alginate gel made by using of calcium chloride
Abstract:
The properties of alginate gel made by using of CaCl2 was studied in this paper. The characteristics of the gel depended on the concentration of CaCl2, temperature and M/G of the alginate. The optimal gelation property was obtained in CaCl2 solution with concentration of 2.0% and at temperature of 50℃. The gel strength of the alginate gel with higher G concentration was better, while the water holding capacity was better with higher M concentration. The change of the gel structure before and after gelation was determined by IR. The results indicated that the OH peak shifted to higher range and the C-H stretching vibration became weaker, which may result from the cross-linking of alginate with calcium.
Key words:  M/G  Alginate gel  CaCl2